A supramolecular chloride–water tape of six- and five-membered rings as template in the crystal structure of di-μ2-hydroxo-bis(diethylenetriamine) dicopper(II) dichloride trihydrate, {[Cu(dien)(μ-OH)]+Cl−}2 · 3H2O

Mircea Braban,Ionel Haiduc,Mathias Noltemeyer,Herbert W Roesky,H.-G Schmidt

doi:10.1016/j.inoche.2007.09.030

A supramolecular chloride–water tape of six- and five-membered rings as template in the crystal structure of di-μ2-hydroxo-bis(diethylenetriamine) dicopper(II) dichloride trihydrate, {[Cu(dien)(μ-OH)]+Cl−}2 · 3H2O

Mircea Braban, Ionel Haiduc + Show 3 more

https://doi.org/10.1016/j.inoche.2007.09.030

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Journal: Inorganic Chemistry Communications	Publication Date: Oct 6, 2007
Citations: 7

Affiliation: Babeș-Bolyai University, University of Göttingen

#Central Moiety #Five-membered Rings + Show 6 more

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Abstract

Water molecules in association with chloride anions form supramolecular self-assembled tapes made of fused five- and six-membered rings, [(H2O)3Cl(OH)] and [(H2O)4Cl(OH)], serving as a template in the crystal structure of dinuclear {[Cu(dien)(μ-OH)]+Cl−}2·3H2O, based upon a Cu2(μ-OH)2 central moiety.

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