Abstract
AbstractThe supermolecular based on sodium molybdate(VI) and sulfate, dibenzo‐18‐crown‐6 was synthesized in acetonitrile and characterized by elemental analysis, IR, 1H NMR, single crystal X‐ray diffraction, indicating that it contains [S2Mo18O62]4+ and [Na(DB18C6)(H2O)]+, where each sodium ion is deviated from the plane defined by the oxygen atoms in the corresponding crown ether. The compound crystallizes in the monoclinic space group C2/c with a=3.29332(10) nm, b=1.90917(6) nm, c=2.63132(7) nm, β=121.6630(10)°, V=14081.8(7) nm3, Z=8, T=293(2) K, and R1 (wR2)=0.0177 (0.1525). The compound exhibits a novel organic‐inorganic structure, in which the crown ether‐sodium complexes are coordinated to the terminal oxygen atoms of Mo18O54 and the oxygen atoms of water molecule.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.