Abstract

CO<sub>2</sub> reduction in alkaline electrolytes enables selective multi-carbon product formation. However, spontaneous reactions between CO<sub>2</sub> and hydroxide to form carbonate species limit energy efficiency and CO<sub>2</sub> conversion efficiencies. Recently published in <i>Joule</i>, near-surface organosuperbases confer similar promotion of C<sub>2+</sub> production in neutral media, where the carbonate issue is circumvented.

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