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Abstract
The parameters of exchange enthalpy, X 12, and entropy, Q 12 have been determined for cyclopentane, tetrahydrofurane and 1,4-dioxane with poly(dimethyl siloxane) around room temperature using inverse gas chromatography technique. The parameters X 12 were compared to the parameters calculated by means of the Berthelot relationship from characteristic pressures of the pure components in the mixtures. The parameters Q 12 were compared to differences of thermal pressure coefficients of the pure components in the mixtures.
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