Abstract
The formation of centres of a new phase in a one-component system has already been investigated in detail, both theoretically and experimentally. In the present work, for a two-component melt system, the free energy required for the formation of a spherical nucleus having a molecules of component A and b molecules of component B has been studied. At the saddle point the values of a ∗, b ∗ and ΔG ∗ have been computed applying the binomial approximation. From the graphical analysis, the composition of the melt for which the composition of the nucleus becomes equal is determined. The LiBr-LiCl binary system has been chosen for the above study.
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