A Study on the Co-Content Optimization of the DD15 Single-Crystal Superalloy

Abstract

The fourth-generation single-crystal superalloy DD15 with 6% Co, 9% Co and 12% Co was cast using the vacuum directionally solidified furnace, while other alloying element’s content remained unchanged. The long-term aging experiment was conducted at 1100 °C for 1000 h after standard heat treatment. The stress rupture tests of the alloy were conducted at 1100 °C/137 MPa and 1140 °C/137 Mpa. The influence of Co content on the microstructure and stress rupture properties of DD15 alloy had been investigated to optimize the Co content to obtain excellent comprehensive performance. The results showed that the primary dendrite arm spacing of the alloy decreases at first and increases afterwards, and the volume fraction of γ-γ′ eutectic decreases with the growth of Co content in the as-cast microstructures. The size, cubic degree and volume fraction of the γ′ phase of the alloy after standard heat treatment all decrease with the increase in Co content. The microstructure stability of the alloy is enhanced with the increase in Co content. No TCP phase was present in the alloy with 12% Co precipitate even after aging 1000 h. The stress rupture lives at two conditions, both reduced in different degrees with the increase in Co content. The effect of Co on the stress rupture life of the alloy improves with the increase in Co content or test temperature. The acicular TCP phase appeared in the 6% Co alloy and 9% Co alloy in the microstructure of the ruptured specimens with different Co contents. Moreover, the TCP phase content in the 6% Co alloy is much more than that in the 9% Co alloy. There is no TCP phase precipitation in the 12% Co alloy. At last, the relationship between microstructure stability, stress rupture properties and Co content of the alloy is discussed. The alloy containing 9% Co is the best choice considering the microstructure stability and stress rupture properties.