Abstract
The temperature dependence of EPR g factor for MgO:V 2+ crystal has been studied theoretically by considering both the static contribution due to the thermal expansion of crystal and the vibrational contributions due to the electron-phonon interaction of the acoustic and optical branches. The static contribution is calculated from the high-order perturbation formula of g factor and the thermal expansion coefficients α( T) at various temperatures. The vibrational contribution of acoustic phonons is obtained by using a Debye model for the lattice vibrations and that ohe optical phonons is calculated by use of a single frequency model. The calculated results show that for the g factor at various temperatures, the static contribution is dominant, but for the temperature dependence of g factor, i.e., ( dg dT ) p or Δg( T)= g( T)− g(0), the vibrational contributions from the acoustic and optical phonons are comparable with the static contribution due to thermal expansion. It appears that a reasonable theoretical explanation for the temperature dependence of g factor should take all of these contributions into account.
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