Abstract
In the relation ηr = 1 + Bm + Dm2 the Β values of the complexes bis(glycinato)Cu(II) and (glycylglycinato)Cu(II) between 10 and 40°C indicate that these complexes are hydrated by two molecules of water at their carboxyl oxygens. Large values of D indicate solute-solute interactions via the axial positions of the cupric square microsymmetry, as the molecules are moving in the liquid streamlines. For both complexes dB/dT was found to be positive in the examined temperature range. This presumably indicates that the examined complexes have a structure breaking effect on the water structure.
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