Abstract
The chemical and electrochemical behaviour of the ruthenium(II) and ruthenium(III) complexes with 2,2′,2″-terpyridine has been studied. Spectrophotometric measurements proved the existence of a protonated ruthenium(II) complex with p K a=2.9. Potentiometric and voltammetric studies showed a difference in the behaviour of the ruthenium(II) complex against chemical and electrochemical oxidation. Potentiometric data showed also that the ruthenium(III) complex may be reduced rapidly and spontaneously.
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