A study of the porosity of nuclear graphite using small-angle neutron scattering

Abstract

Small-angle neutron scattering (SANS) measures porosity in nuclear graphites, including both open pores, caused by escaping decomposition gases, and internal cracks (in coke particles) generated by anisotropic thermal contraction along the c-direction (Mrozowski Cracks). Porosity changes on the length scale observable by SANS must control the development of internal stresses and hence of cracking in AGR graphite due to irradiation (both fast neutron displacements of carbon atoms and radiolytic corrosion by CO2). Such cracking may cause premature reactor shutdown. SANS measurements show that porosity is fractal on a length scale between ∼0.2 and 300nm, presumably due to Mrozowski cracks – because the fractal index of the SANS signal depends only on the porosity of the graphitic filler. We report here two novel uses of the SANS technique as applied to reactor graphite – contrast matching with D-toluene (to measure the fraction of the porosity open to the surface) and the temperature dependence of the scattering (to measure pore width changes up to 2000°C). These results provide important new information on AGR graphite porosity and its evolution during irradiation.