Abstract
AbstractNitrosobenzene (NB) and nitroso‐tetr‐butane (NtB) were used to trap the photogenerated rhenium pentacarbonyl radical. Self trapped radicals and spin adducts were studied in detail by EPR spectroscopy. In methylene chloride, both nitroxide and anilino spin adducts can be observed with NtB at −30°. In contrast, only the nitroxide spin adduct of nitrosobenzene was observed in either hexane, or methylene chloride solution. This solvent controlled spin adduct chemistry, can be explained in terms of the solute‐solvent interaction.
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