Abstract

The local structure of Nb3Ge intermetallic superconductor has been studiedby Ge K-edge absorption spectroscopy. Extended x-ray absorption finestructure (EXAFS) experiments show two Ge–Nb distances. In additionto the crystallographic distance of ∼2.87 Å, there exists a second Ge–Nbdistance, shorter than the first by ∼0.2 Å, assigned to a phase with short-rangesymmetry related to local displacements in the Nb–Nb chains. The x-rayabsorption near-edge structure (XANES) spectrum has been simulated by fullmultiple-scattering calculations considering the local displacements determined bythe EXAFS analysis. The XANES spectrum has been well reproducedby considering a cluster of 99 atoms within a radius of about 7 Å fromthe central Ge atom and introducing determined local displacements.

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