Abstract
Equilibria between 2-hydroxy-1,4-naphthoquinone monoxime and proton or bivalent metal ions have been investigated potentiometrically at various ionic strengths and solvent compositions (dioxan : water). The method of Bjerrum and Calvin, as modified by Irving and Rossotti, was used to determine the values of n and p L. The stability constants were calculated using an IBM 360 computer, by the weighted least-squares method. The values of S min = X 2 were also calculated. The stability constants were found to decrease in the order. Cu > Ni > Co > Zn > Pb > Cd > Mn > Mg Other thermodynamic parameters and ligand field stabilization energies were calculated from the stability constants.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
