Abstract
Due to the simultaneously unknown individual ion activity coefficients and liquid-junction potentials, a reasonable convention must be introduced defining the former in order to permit the calculation of the latter. The Guggenheim convention is analysed and chosen.Examples are reported of determination of potentials arising at junctions between concentrated strong acids and salt bridges. Liquid junction potentials set up between two concentrated strong acids at identical molalities are also considered, on the basis of a modified Henderson equation.
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