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Abstract
The composition and morphology of carbonaceous products formed upon the thermal decomposition of tricresyl phosphate, tributyl phosphate, and tributyl phosphite at a temperature of 760°C in a fused-silica flow reactor have been studied for the first time. It has been shown that they contain P-O-C bonds and are graphite-like clusters with a size of ≤1 nm self-assembled into spherical or fibrous structures.
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