Abstract
Effective utilization of the high energy density of ethanol as a fuel for polymer electrolyte fuel cells is contingency of complete oxidation of ethanol to carbon dioxide. Major problems associated with the development of electrocatalysts for ethanol oxidation are the high content of Pt and partial oxidation of ethanol to acetaldehyde and acetic acid instead of complete oxidation to carbon dioxide via the 12 electron process. Despite extensive work on ethanol oxidation catalysts, it is difficult to get C-C bond splitting without compromising on the Pt content. In this report, Au/C nanoparticles with Pt monolayer: Au/C@Pt(II) and sub-monolayer: Au/C@Pt(IV) were studied as electrocatalysts for ethanol oxidation reaction (EOR). Au/C@Pt(II) and Au/C@Pt(IV) were synthesized using a Cu mediation electrochemical method. Electrochemical testing of these electrocatalysts showed that Au/C@Pt(II) had substantially higher activity towards EOR than Au/C@Pt(IV). The effect of Pt cluster sizes on the Au surface and the tensile strain on Pt due to the underlying Au and their effect on EOR will be discussed. The mechanism of EOR on these electrocatalysts was also studied using in-situ FTIR to understand whether there is complete or partial oxidation of ethanol.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
