Abstract
Abstract3‐Benzoyl‐2‐oxa‐3‐azabicyclo[2.2.2]oct‐5‐ene undergoes cycloaddition with benzonitrile oxide to afford a mixture of syn and anti regioisomeric cycloadducts. The anti cycloadducts were easily elaborated to stereodefined isoxazoline‐based carbocyclic aminols that serve as synthons for the linear construction of purine nucleosides. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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