Abstract
An approach joining highly diastereoselective Mukaiyama aldol reaction (process A ) to the following radical debromination reaction (process B ) provides a reliable way to the stereoselective divergent synthesis of polypropionate frameworks. A practical and reliable synthesis of the complete set of propionate stereotetrads from enantiopure syn- and anti-2-methyl-3-methoxy-3-phenylpropanals was achieved by using the straightforward strategy.
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