Abstract

A new cationic Fe4L6 cage molecule was synthesised from 4,4′-diaminobiphenyl, 2-formylpyridine and iron(II). The cage exists as a system of interconverting diastereomers in solution. The system adapts to the addition of anionic guest molecules, expressing a new combination of diastereomers that synergistically bind the guest molecules. Not only do the cage diastereomers interconvert, the volume of the individual cages adapts physically through the rotation of bonds, providing a tailored binding pocket for the guest lined with hydrogen-bond donors. A model for the resulting complex network of species was developed that allowed the system to be fully described. The anion binding constants and the kinetics of both diastereomer interconversion and guest exchange were measured.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.