Abstract
Abstract We have synthesized an asymmetric dinucleating ligand connecting the N3 and N4 coordination sites with an amido linkage and characterized the corresponding dicopper(I) complex by spectroscopic methods. The dicopper(I) complex reacted with O2 at low temperature to yield a (μ-peroxo)Cu2 species with a μ-η1:η2-binding mode. We also explored an effect of this amide linkage that contributed to stabilizing a μ-η1:η2-Cu2O2 adduct.
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