Abstract

AbstractThe synthesis and structural characterization of the new complexes [Ni(iPr2Im)2(η2‐C,C‐Me2C=CHCOMe)] (2), [Ni(iPr2Im)2(η2‐H2C=CH‐(4‐C5H4N)] (3) and [Ni(iPr2Im)2(η2‐N,N′‐N2CPh2)] (4) is reported. Complex 4 is remarkably stable under an inert gas atmosphere and does not undergo nitrogen loss under thermal or photochemical conditions.

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