Abstract

Abstract A TANOL derivative of benzo-15-crown-5 shown in the Fig. 1, was synthesized, and the complex formation between the spin labeled crown ether and the alkali metal isocyanate was studied by ESR technique. The potassium complex revealed a strong spin–spin interaction due to formation of the sandwiched dimer and the structure was investigated on the basis of the ESR parameters of the triplet cluster.

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