Abstract

A novel (4, 12)-connected metal-organic framework, {(NH4)2·[Co11(μ4-OH)6(CN)6(trz)12]}n, was solvothermally constructed from unusual CoII8 cubes, octahedral CoII1 subunits, and μ3-N1,N2,N4-triazolate (trz) connectors. Strong antiferromagnetic coupling between the neighboring CoII ions results in an absence of long-range magnetic ordering, leading to a strong spin-frustration with f>62.

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