Abstract
在连续介质理论基础上，根据热力学基本原理，用一个外加电场Eex将非平衡态2[E2^non,D2^non]变成约束平衡态[E2^＊，D2^＊]，推导出了正确普适的溶剂重组能公式．基于球-界面近似，推导出了正确的溶剂-导体界面电子转移溶剂重组能公式．和Marcus的公式相比，本文的结果多了（es-eop）／（eop（es-1））因子．对极性溶剂，预测的溶剂重组能约为Marcus模型所得结果的一半．以C343（Coumarin343）-TiO2体系为算例，计算了溶剂重组能并与实验值进行了比较．
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