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Abstract
The interaction of VO 2+ with adenosine-triphosphate (ATP), -diphosphate (ADP), and -mono- phosphate (AMP) has been studied as a function of pH by differential UV-absorption spectroscopy. It could be demonstrated that at pH > 3 an interaction of the cation with the adenine ring takes place in the case of the VO/ATP and VO/ADP systems. At pH ⪯ 3 the metal-to-ligand interaction occurs only through the phosphate moieties of the nucleotides; this is also the behavior observed for the VO/AMP system, even at higher pH values. Results for the VO 2+/P 2O 7 4− and VO 2+/D-Ribose interactions are also presented.
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