Abstract
Cu2ZnSnS4 (CZTS) has been proposed as an alternative earth-abundant absorber material for thin film solar cells. In this paper, we report a facile solvothermal method to produce impure-free kesterite CZTS nanocrystals. Optical band gap of the obtained high quality CZTS nanocrystals is 1.52 eV determined by UV–VIS–NIR absorption spectrum, which is match well with the optimum for photovoltaic solar conversion in a single-band-gap device. We closely systematically investigated both the concentration of Sulfur (S) and the species of precursor Tin (Sn) and their impact on the final products. Furthermore, CZTS nanocrystals based layers hybrid junction solar cells were fabricated by a layer-by-layer dip-coating method. The enhancement in photovoltaic performance was also explore through the solid state ligand exchange which was used 1, 2-ethanedithiol (EDT) to treat the CZTS nanocrystals layer. We achieved the best power conversion efficiencies (PCE) of 1.73% fabricated with the EDT treated CZTS nanocrystals layer, which is approximately 5 fold than the comparative devices without treatment.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
