Abstract

In this study, we explored magnetic nanoparticles translocating through a nanopore in the presence of an inhomogeneous magnetic field. By detecting the ionic current blockade signals with a silicon nitride nanopore, we found that the translocation velocity that is driven by magnetic and hydrodynamic forces on a single magnetic nanoparticle can be accurately determined and is linearly proportional to the magnetization of the magnetic nanoparticle. Thus, we obtained the magneto-susceptibility of an individual nanoparticle and the average susceptibility over one hundred particles within a few minutes.

Highlights

  • The most important issue for magnetic materials is an understanding of the magnetic and physical properties of a nanometer-sized particle because the use of magnetic nanoparticles (MNPs) in many applications depends predominantly on their inherent magnetic properties

  • We found that the magnetic force enables the MNPs to move more rapidly and that the velocity is linearly proportional to the magnetization of a MNP

  • We have investigated the properties of magnetic nanoparticles translocating through a solid-state nanopore in the presence of an inhomogeneous magnetic field

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Summary

Introduction

The most important issue for magnetic materials is an understanding of the magnetic and physical properties of a nanometer-sized particle because the use of magnetic nanoparticles (MNPs) in many applications depends predominantly on their inherent magnetic properties. The size and surface charge state of a nanoparticle can be routinely characterized by dynamic light scattering (DLS) and zeta-potentiometry, respectively. These methods can provide information on the distributions and the average values of the size and charge number of each particle. Unlike DLS and zeta-potentiometry, these techniques, they have excellent sensitivities, are limited to the average properties of a large number of MNPs. To the best of our knowledge, the resultant data from these techniques do not provide sufficient information on the magnetism of a MNP, which may be considered as a critical bottleneck in facilitating the use of MNPs in various industrial applications

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