A sol-gel strategy for constructing a hydroxyapatite nanowire/aramid nanofiber electric insulating composite with excellent flame retardancy and mechanical property

Abstract

With the increasing demand for high power and miniaturization of modern large-scale electrical equipment, preparing high-performance electrical insulation materials with high thermal stability and excellent mechanical properties has become an urgent problem. In this study, hydroxyapatite (HAP) nanowires and aramid nanofibers (ANF) multifunctional composites were prepared by sol-gel-membrane strategy. Aramid fibers containing an amide structure and HAP can form an ordered hydrogen bonding network and exhibit strong hydrogen bonding. The prepared HAP/ANF nanocomposite films with nanowire/nanofiber network skeleton and laminate structure have good tensile strength (69.6 MPa), dielectric breakdown strength (65.7 kV mm−1), and processing properties. Particularly emphasized is that the multifunctional HAP/ANF nanocomposite films are fireproof and high-temperature resistant, and the interfacial hydrogen-bonding enhancement between HAP nanowires and aramid fibers facilitates the construction of multifunctional insulating materials.