A simulation study of electrostatic effects on mixed ionic micelles confined between two parallel charged plates.

Abstract

Confined colloidal systems have been the subject of extensive theoretical and experimental research, and the recent observation of long-range like-charge attraction in such systems has only highlighted their peculiar behavior. On the other hand, surfactant solutions are often used in small confined space, yet their behavior in confinement has received relatively little attention. A distinct feature of confined self-assembling systems is that the aggregates are capable of adjusting their composition, size, and shape in response to their external environment, which may lead to very different phase characteristics compared to bulk solutions. The primary objective of this study is to explore the effects of varying micelle composition on the structural behavior of a confined mixed ionic micellar solution. Mesoscale canonical Monte Carlo simulations were used to probe the structure of the confined solution, while a molecular-thermodynamic model was used to systematically account for the change in micelle size as we varied its composition. Significant micelle ordering was found under certain conditions, which implies that large deviations from the minimum-energy micelle configuration may not be entropically favorable. Accumulation of micelles along the midplane was observed when the confining walls are weakly charged, suggesting that micelle shape transformation should be considered in more detail. On the other hand, with high wall charge density, apparent attraction was found between like-charged micelles and wall. These findings point to the need for a more quantitative theoretical treatment in describing surfactant self-assembly in confined geometries.