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Abstract
A simple, small-bandgap porphyrin-based conjugated polymer with ethylnyl linkers is prepared for application in organic electronics. Beneficial from quinoid resonance form, the polymer showed near-infrared absorption up to 1000nm and strong photoluminescence emission with a quantum yield of 0.2%. The polymer can be successfully applied to several electronic devices, such as organic field-effect transistors with ambipolar charge transport, organic solar cells with a high external quantum efficiency of 0.58 at 970nm, and organic photodetectors with high responsibility and detectivity.
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