Abstract
In this paper, a new approach for incorporating off-energy-shell effects into energy sudden (ES) scaling relations is described. The framework for the new approach is provided by the first order Born approximation which allows for the relating in an approximate fashion of off-energy-shell and on-energy-shell T-matrix elements. The relationship between this approach and a former procedure is discussed. Application of the off-shell corrected ES relation is made to the vibrational-rotational scattering of He–H2.
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