A simple polyacrylamide gel route for the synthesis of MgAl2O4 nanoparticles with different metal sources as an efficient adsorbent: Neural network algorithm simulation, equilibrium, kinetics and thermodynamic studies

Abstract

• A polyacrylamide gel method have been used to synthesize the MgAl 2 O 4 nanoparticles. • An artificial neural network model of phase purity of MgAl 2 O 4 was constructed. • The microstructure and adsorption performance of MgAl 2 O 4 nanoparticles were compared. • An adsorption mechanism of MgAl 2 O 4 nanoparticles was proposed. The MgAl 2 O 4 nanoparticles with different particle sizes prepared by a polyacrylamide gel method with different metal salts as raw materials which was used to study its efficiency as an adsorbent for removal of Congo red, acid orange 7 and acid fuchsin from wastewater. It was difficult to obtain pure MgAl 2 O 4 nanoparticles with basic magnesium carbonate or aluminum acetate coupled with other metal salts. Based on the molecular weight, coordination number, ion radius and the number of water of crystallization for the metal salt and the phase purity of the target product, a neural network prediction model was established to predict the effect of synthesis parameters on the phase purity of MgAl 2 O 4 . The microstructure characterization confirmed that the minimum particle size of MgAl 2 O 4 nanoparticles prepared with aluminum nitrate and magnesium sulfate as metal salts was about 22 nm, and the maximum particle size of MgAl 2 O 4 nanoparticles prepared with aluminum nitrate and magnesium chloride as metal salts was about 50 nm. Adsorption experiments of MgAl 2 O 4 nanoparticles were performed as a function of process parameters: various dyes including Congo red, acid orange 7 and acid fuchsin, adsorption time, particles size, initial dye concentration, initial adsorbent concentration, pH value and reaction temperature. The thermodynamic studies showed that the adsorption of MgAl 2 O 4 nanoparticles for removal of Congo red from wastewater is an exothermic and spontaneous process. The maximum adsorption capacity of 89.043 mg/g for the MgAl 2 O 4 nanoparticles was found at 1 g/L of initial adsorbent concentration, 100 mg/L of initial dye concentration, 6.9 of pH, and 299.8 K of temperature for removal of Congo red from wastewater. The adsorption of Congo red, acid orange 7 and acid fuchsin can be assigned to the synergistic effect of electrostatic interaction, pore filling and ion exchange. This present work provides a technical reference for the synthesis of other metal oxide nanoparticles using metal salts with different acid groups.