A simple model to predict chromate partitioning in selected soils from China

Abstract

Due to its mobility and toxicity, chromate [Cr(VI)] partitioning in soils, especially in the vadose zone, is an important environmental concern. The aim of this study was to develop a mechanism-based multi-surface complexation model using published parameters to predict the soil/water partitioning of Cr(VI) in 12 soils (previously depleted of organic matter) from China. The retention of Cr(VI) in soils was attributed to two reactive oxide surfaces: goethite and hydrous ferric oxide (HFO); however, modeling results showed that the best prediction was obtained with goethite alone, whereas the addition of HFO resulted in an overestimation of adsorption in some soils. Cr(VI) adsorption onto goethite could be described using our previously proposed CD-MUSIC model. In the absence of a specific value for the soil-reactive surface area of goethite, a general value of 45.8m2/g was used. The available phosphate in soils was identified as a strong competitor for Cr(VI) adsorption; thus, for soils with a low Fe/P ratio (<1) the effect of phosphate on Cr(VI) retention should not be neglected. The simple method presented herein can be applied to soils with a wide range of properties, pH values, and Cr(VI) loading concentrations.