Abstract

A simple method ensuring a high accuracy of determination of the mass transfer coefficients, k d , and the surface reaction constants, k r , during crystallization has been elaboarated. The relative standard deviations between the crystal growth rates calculated from the equation Δ c = R g / k d + ( R g / k r ) 1/ r and those experimentally obtained and described by a relationship R g = k g (Δ c) g do not exceed 1.5%. The values of k d and k r estimated from the proposed integral method are close to those directly determined from the measurements of the rates of crystal dissolution and growth.

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