Abstract
We have used a supersonic jet to matrix isolate either well defined hydrogen bonded aggregates or the monomeric species of carboxylic acids (formic acid or acetic acid, respectively). By varying several parameters of the pulsed deposition we have shown that the pulse duration has the major influence on the aggregation in the gas phase. This allowed us to generate either the monomer or the dimer from the same gas mixture and to report for the first time the infrared spectra of matrix isolated formic acid cyclic dimers.
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