Abstract
Ammonia gas sensors are very essential in many industries and everyday life. However, their complicated fabrication process, severe environmental fabrication requirements and desorption of residual ammonia molecules result in high cost and hinder their market acceptance. Here, laser direct writing is used to fabricate three parallel porous 3D graphene lines on a polyimide (PI) tape to simply construct an ammonia gas sensor. The middle one works as an ammonia sensing element and the other two on both sides work as heaters to improve the desorption performance of the sensing element to ammonia gas molecules. The graphene lines were characterized by scanning electron microscopy and Raman spectroscopy. The response and recovery time of the sensor without heating are 214 s and 222 s with a sensitivity of 0.087% ppm−1 for sensing 75 ppm ammonia gas, respectively. The experimental results prove that under the optimized heating temperature of about 70 °C the heaters successfully help implement complete desorption of residual NH3 showing a good sensitivity and cyclic stability.
Highlights
Ammonia gas plays a vital role in numerous fields, including nitric acid manufacturing, petrochemical industries, plastics, explosives, textiles, as a refrigerating fluid and in gallium nitride, etc [1,2], but exposure to it at higher concentrations will lead to serious damage to the human eyes, skin and respiratory system [3]
Sensors 2018, 18, 4405 (PANI/MWCNT, PANI/SnO2, PANI/ZnO, PABS/SWCNT) with synergistic effects [14,15,16,17] have been verified to be capable of sensing ammonia gas
We propose a facile method to fabricate three parallel porous 3D graphene lines on a thin PI tape by using the laser direct writing technique to construct a flexible ammonia gas sensor, in which the sandwiched line acts as a sensing element, and the other two lying beside the sensing element act as heaters to help achieve complete desorption of ammonia molecules
Summary
Dezhi Wu 1, * , Qianqian Peng 1 , Shan Wu 1 , Guangshun Wang 1 , Lei Deng 1 , Huiling Tai 2 , Lingyun Wang 1 , Yajie Yang 2 , Linxi Dong 3 , Yang Zhao 1, * , Jinbao Zhao 4 , Daoheng Sun 1 and Liwei Lin 1,5.
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