A simple and efficient transfer method for fabricating stretchable AgNW patterns on PDMS using carboxylated cellulose nanofibers as a sacrificial layer.

Abstract

Silver nanowire (AgNW) networks are one of the most promising materials of transparent electrodes in flexible applications. However, they still face challenges in fabricating AgNW transparent conductive films (TCFs) with excellent comprehensive performance on stretchable substrates. In this work, we developed an efficient and simple water-assisted method to completely transfer AgNW films from glass to polydimethylsiloxane (PDMS). Carboxylated cellulose nanofibers (CNF-C) are introduced between the AgNW network and glass as a sacrificial layer, which is dissolved in water in the transfer process, releasing the AgNW network on the PDMS. The transferred AgNW networks show an increase of sheet resistance less than 30% and a slight decrease of transmittance. The stretchable AgNW TCFs exhibited good opto-electrical performance with a figure of merit of about 200, low surface roughness, good film uniformity, long-term stability, electrical stability and mechanical performance. Two patterning approaches based on the transfer method were proposed and fine stretchable AgNW patterns with a linewidth of 200 μm were fabricated. The fabricated stretchable AgNW patterns were used in flexible wires, a film heater and sensors as a demonstration.