A simple and efficient resin precoating treatment on anodised substrate surfaces for enhancing the adhesive bonding strength between aluminium and mild steel

Abstract

The primary concerns in the adhesive bonding of metal substrate surfaces include inadequate wettability, compatibility, and insufficient mechanical interaction at the bonding interface. These factors are significant barriers to developing and manufacturing high-strength bonded materials. This study utilized three different anodising techniques, such as H3PO4, H2SO4, and NaOH, to produce micro-rough surfaces that improve the adhesive bond between aluminium alloy and mild steel. A novel and a simple method known as resin pre-coating (RPC) were used to increase the wetting and effectively seal the micro-cavities of mild steel and aluminium surfaces. RPC solution comprises 10 wt% resin (Absence of hardener) and 90 wt% acetone, which facilitated the penetration of resin into the microcavities surface, thereby increasing the bonding surfaces. Subsequently, the normal adhesive mixed with hardener is placed onto the metal surfaces. The adhesive bonding strength was evaluated by conducting the single lap shear test under various surface conditions. The surface topography of anodised samples were examined by X-ray Photoelectron Spectroscopy (XPS), Atomic Force Microscopy (AFM), Field Emission Scanning Electron Microscopy (FESEM), and Contact Angle Goniometer. Experimental results of a lap shear test revealed that the adhesive bond strength of H3PO4 anodised samples is greater than those of H2SO4 and NaOH anodised samples. Furthermore, the RPC treatment increased the bond strength of all H3PO4 anodised samples by 46.91–47.26 %, for H2SO4 samples by 39.71–42.22 %, and NaOH samples by 37.89–48.51 %, compared to the readings obtained without RPC treatment. The combined use of H3PO4 and RPC treatment results in the greatest bonding strength of 16.765 MPa, which is 9.17 % and 20.10 % greater than the bonding strength of H2SO4 and NaOH anodised samples. Thus, the H3PO4 anodised method improved the wetting ability of the metal surface and maximized the use of contact area on the rough substrate surfaces. The anodising treatment details in this study are inexpensive and simple for creating strong adhesive joints in aviation, automobile, and aerospace applications.