Abstract
The chiral complex 2 containing an optically pure P-chiral diphosphine ligand has been prepared efficiently in three steps by the asymmetric Diels−Alder reaction between coordinated phenyldivinylphosphine on a cationic intermediate: (i) AgClO4; (ii) 1-phenyl-3,4-dimethylphosphole; (iii) HCl.
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