Abstract
A novel coordination polymer, namely, [Ag0.5(H2O)][Ag1.5(L)(H2O)]·2H2O (1) (H2L = 4'-((2-carboxyphenoxy)methyl)biphenyl-2-carboxylic acid) has been successfully synthesized at room temperature. In compound 1, L anions bridge Ag(I) cations to form a one dimensional (1D) double chain structure, while there is an infinite Ag(I) chain joined by argentophilic interaction. Neighboring double chains are further extend into two dimensional (2D) supramolecular layers via intermolecular hydrogen-bonding interactions. Compound 1 has been characterized by infrared spectrum (IR), elemental analysis and powder X-ray diffraction (PXRD) analysis, and the luminescent properties of 1 were measured in detail. The luminescent intensity decreases regularly along with temperature increasing, which displays that compound 1 is a potential luminescent thermometer.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.