Abstract
Tholence et al. and Yao et al. observed a significant drop in resistance around 250 K and 230 K respectively on superconducting Hg-based compounds. Yao et al. believed that this drop in resistance is due to the presence of the free-state liquid mercury or Hg-Au alloys in the sample. We report here the electrical resistivity measurements on single phase (as determined by X-ray powder technique) Hg-1223, which has shown a partial or total drop in resistivity around 200 K but with no significant observation of diamagnetic signal. On the other hand, an internal friction peak around 203 K was observed in our internal friction experiment. We are sure that the drop in resistance for our Hg-1223 sample around 200 K is not due to the presence of liquid mercury or Hg–Au alloys in the sample since we did not use the gold foil or silver foil to enwrap our sample. We rather believe that the drop in resistivity is due to superconductivity or other mechanisms.
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