Abstract
A previously proposed scheme for coupling short-range (sr) density functionals with wavefunction-based long-range (lr) ab initio methods has been extended by (a) developing a new gradient-corrected sr functional of the Perdew-Burke-Ernzerhof (PBE) type and (b) introducing coupled-cluster (CC) approaches (CC with single and double excitations (CCSD), and with additional perturbative triples (CCSD(T))) at the ab initio side. The results show that mixing-in of lr-ab initio correlation helps to remove deficiencies of currently used density functionals for the treatment of van-der-Waals interactions. Compared to full ab initio calculations, the basis set dependence is weaker so that the accuracy of the mixed results surpasses that of the ab initio ones for basis sets of triple-zeta quality.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
