A short overview of the lead iodide residue impact and regulation strategies in perovskite solar cells

Abstract

Lead iodide (PbI2) is a vital raw material for preparing perovskite solar cells (PSCs), and it not only takes part in forming the light absorption layer but also remains in the grain boundary as a passivator. In other words, the PbI2 content in the precursor and as formed film will affect the efficiency and stability of the PSCs. With moderate residual PbI2, it passivates the bulk/surface defects of perovskite, reduces the interfacial recombination, promotes the perovskite stability, minimizes the device hysteresis, and so on. Deficient PbI2 residue will reduce the interfacial passivation effect and device performance. In addition to facilitating the non-radiative recombination, over PbI2 residue can also lead to electronic insulation in the grain boundary and deteriorate the device performance. However, the impact and regulation of PbI2 residue on the device performance and stability is still not fully understood. Herein, a comprehensive and detailed review is presented by discussing the PbI2 residue impact and its regulation strategies (i.e., elimination, facilitation and conversion of the residue PbI2) to manipulate the PbI2 content, distribution and forms. Finally, we also show future outlooks in this field, with an aim to help further the progression of high-efficiency and stable PSCs.