Abstract
A series of nine 3D metal-organic frameworks based on Ln3+ and 2-diodoterephthalate (2-I-bdc) with general formula {[Ln2(2-I-bdc)3(H2O)]·xH2O·yCH3CN} (Ln = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy and Ho, 1–9) were obtained. According to X-ray diffractometry, all these complexes belong to two structural types (La to Nd and Sm to Ho, respectively). Some of complexes in the 1–9 series demonstrate luminescent properties.
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