Abstract

An extended test-particle method is used to predict the inter- andintramolecular correlation functions of freely jointedhard-sphere-Yukawa-chain fluids by calculating the segmental densitydistributions around a fixed segment. The underlying density functionaltheory for chain fluids is based on a modified fundamental measuretheory for the hard-sphere repulsive and a mean-field approximation forattraction between different segments. The calculated intra- andinter-molecular distribution functions agree well with the results fromMonte Carlo simulations, better than those from alternative approaches.

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