Abstract

The Ti 2p electron shake-up spectrum in TiCl 4 is calculated using SCF Xα SW method. Results showed that the low-energy satellite can be ascribed to ligand → metal charge-transfer transitions. However, the nature of the intense peak at 9.8 eV cannot be explained within the one-electron model. An anomaly is noted in the eiperimental spectra of the titanium halides.

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