Abstract
In the trinuclear title complex, di-μ-acetato-1:2κ2 O:O′;2:3κ2 O:O′-bis{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(methanylylidene)]diphenolato}-1:2κ6 O 1,N,N′,O 1′:O 6,O 6′;2:3κ6 O 6,O 6′:O 1,N,N′,O 1′-2-gadolinium(III)-1,3-dizinc hexafluoridophosphate methanol monosolvate monohydrate, [GdZn2(C22H24N2O4)2(CH3COO)2]PF6·CH3OH·H2O, the two ZnII ions are located in the inner N2O2 cavities of two 6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(methanylylidene)]diphenolate (L) ligands. Both ZnII ions are five-coordinated by two O atoms and two N atoms from the L ligand and one O atom of an acetic acid molecule, giving rise to a square-pyramidal geometry around the ZnII ions. The GdIII ion is nine-coordinated by four O atoms from the outer O2O2 sites of one ligand, and three O atoms from another ligand, in which there is one non-coordinating methoxy O atom. Two further O atom from different acetate ligands complete the nine-coordinate environment.
Highlights
Key Laboratory of Functional Inorganic Material Chemistry (HLJU), Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People’s Republic of China
[GdZn2(C22H24N2O4)2(CH3COO)2]PF6CH3OHH2O, the two ZnII ions are located in the inner N2O2 cavities of two 6,60 -dimethoxy-2,20 -[cyclohexane-1,2-diylbis(methanylylidene)]diphenolate (L) ligands
Both ZnII ions are fivecoordinated by two O atoms and two N atoms from the L
Summary
R factor = 0.053; wR factor = 0.157; data-to-parameter ratio = 19.7. In the trinuclear title complex, di--acetato-1:22O:O0 ;2:32O:O0 -bis{-6,60 -dimethoxy-2,20 -[cyclohexane-1,2-diylbis0. [GdZn2(C22H24N2O4)2(CH3COO)2]PF6CH3OHH2O, the two ZnII ions are located in the inner N2O2 cavities of two 6,60 -dimethoxy-2,20 -[cyclohexane-1,2-diylbis(methanylylidene)]diphenolate (L) ligands. Both ZnII ions are fivecoordinated by two O atoms and two N atoms from the L ligand and one O atom of an acetic acid molecule, giving rise to a square-pyramidal geometry around the ZnII ions. The. O2O2 sites of one ligand, and three O atoms from another ligand, in which there is one non-coordinating methoxy O atom. Two further O atom from different acetate ligands complete the nine-coordinate environment
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