Abstract
Abstract Treatment of ΔΔ-[NiII{CoIII(aet)2(R,R-chxn)}2](ClO4)4 (Haet = 2-aminoethanethiol, R,R-chxn = 1R,2R-cyclohexanediamine) with Cu(ClO4)2 in water gave ΔΔ-[CuII{CoIII(aet)2(R,R-chxn)}2](ClO4)4 (1), in which a central copper(II) ion is surrounded by four aliphatic thiolato donors in a twisted square-planar geometry. Complex 1 was converted to ΔΔ-[CuICl{CoIII(aet)2(R,R-chxn)}2](ClO4)2 (2) by treatment with NaCl in water, while 2 was reverted back to 1 by treatment with NaClO4.
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