Abstract

A route to the functionalised cyclopentenone derivative, (2 S)-( 2 3 )-dibenzyloxy-5-(hydroxymethyl)cyclopentene-4-enone ethylene acetal, has been developed from a deoxyinosose that is readily accessible. The carbocyclisation procedure was less efficient in affording (2 S)-(2, 3 4 ,5)-2,3,4,5-tetrahydroxy-2,3- O-isopropylidenecyclohexanone from 6-deoxy-1,2:3,4-di- O-isopropylidene-β- l- arabino-hex-5-enopyranose. Various reactions were carried out on (2 S)-(2,4, 5 3 )-2,3-di-benzoyloxy-5-hydroxy-4-toluene- p-sulphonyloxycyclohexanone ethylene dithioacetal.

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