Abstract
β,β'-Phenylene bridged hexaphyrin[1.0.1.0.1.0] (naphthorosarin), an expanded porphyrin possessing C3v-symmetry, has been shown to possess unique electronic features. We now report a bimetallic Rh(i)-complex of naphthorosarin retaining 24 π-antiaromatic characteristics. The two Rh(i) cations reside on opposite sides of the macrocyclic π-system and are separated at a distance consistent with a possible Rh(i)-Rh(i) metallic bond interaction.
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